Ecological Risk Assessment and Source Identification of Heavy Metals in Soils from Shiyang River Watershed in Northwest China.

Shiyang River Watershed is an important ecological barrier and agricultural production area in Northwest China, and the study of soil heavy metal content, distribution, and sources is important for agricultural product safety, pollution control, and ecosystem health. In this paper, 140 soil samples were collected from 28 stations to assess the level of heavy metal (Arsenic (As), Copper (Cu), Lead (Pb), Cadmium (Cd), Chromium (Cr), Mercury (Hg), Nickel (Ni), Zinc (Zn)) contamination, pollutant sources and influencing factors of soil in Shiyang River Watershed through determination of the metal contents and statistical analysis. The results indicated that the soils in the study area are typical saline soils in arid zones. The enrichment factors (EF) of As, Cr, Cu, Ni, Zn, and Pb indicate no contamination, and the EFs of Cd and Hg suggested minor contamination. Although the concentrations of Cd and Hg in soil are lower than others, they are more biotoxic and exhibit a moderate-high ecological risk. The index of geoaccumulation (Igeo) values reflect that most of the stations, especially the three groups of samples from depths of 10-20 cm, 20-40 cm, and 40-80 cm, are below the contamination threshold for all heavy metals. The chemical speciation of heavy metals, principal component analysis, and correlation analysis showed that Cr, Cu, Pb, Cd, Ni, and Zn mainly come from the natural accumulation upon weathering of soil-forming matrices. Hg and As mainly come from anthropogenic contributions. The effect of agricultural crop cultivation on soil heavy metal contamination is mainly through farm irrigation and crop-soil interactions, which accelerate the release of heavy metals through the weathering of soil-forming parent material and irrigation, which transports the heavy metals below the surface. The results of this study can provide a scientific basis for the involved authorities to formulate reasonable policies on environmental protection and pollution control.

Soil texture and microorganisms dominantly determine the subsoil carbonate content in the permafrost-affected area of the Tibetan Plateau.

Under climate warming conditions, storage and conversion of soil inorganic carbon (SIC) play an important role in regulating soil carbon (C) dynamics and atmospheric CO2 content in arid and semi-arid areas. Carbonate formation in alkaline soil can fix a large amount of C in the form of inorganic C, resulting in soil C sink and potentially slowing global warming trends. Therefore, understanding the driving factors affecting carbonate mineral formation can help better predict future climate change. Till date, most studies have focused on abiotic drivers (climate and soil), whereas a few examined the effects of biotic drivers on carbonate formation and SIC stock. In this study, SIC, calcite content, and soil microbial communities were analyzed in three soil layers (0-5 cm, 20-30 cm, and 50-60 cm) on the Beiluhe Basin of Tibetan Plateau. Results revealed that in arid and semi-arid areas, SIC and soil calcite content did not exhibit significant differences among the three soil layers; however, the main factors affecting the calcite content in different soil layers are different. In the topsoil (0-5 cm), the most important predictor of calcite content was soil water content. In the subsoil layers 20-30 cm and 50-60 cm, the ratio of bacterial biomass to fungal biomass (B/F) and soil silt content, respectively, had larger contributions to the variation of calcite content than the other factors. Plagioclase provided a site for microbial colonization, whereas Ca2+ contributed in bacteria-mediated calcite formation. This study aims to highlight the importance of soil microorganisms in managing soil calcite content and reveals preliminary results on bacteria-mediated conversion of organic to inorganic C.

Soil texture influences soil bacterial biomass in the permafrost-affected alpine desert of the Tibetan plateau.

Under warm climate conditions, permafrost thawing results in the substantial release of carbon (C) into the atmosphere and potentially triggers strong positive feedback to global warming. Soil microorganisms play an important role in decomposing organic C in permafrost, thus potentially regulating the ecosystem C balance in permafrost-affected regions. Soil microbial community and biomass are mainly affected by soil organic carbon (SOC) content and soil texture. Most studies have focused on acidic permafrost soil (pH < 7), whereas few examined alkaline permafrost-affected soil (pH > 7). In this study, we analyzed soil microbial communities and biomass in the alpine desert and steppe on the Tibetan plateau, where the soil pH values were approximately 8.7 ± 0.2 and 8.5 ± 0.1, respectively. Our results revealed that microbial biomass was significantly associated with mean grain size (MGS) and SOC content in alkaline permafrost-affected soils (p < 0.05). In particular, bacterial and fungal biomasses were affected by SOC content in the alpine steppe, whereas bacterial and fungal biomasses were mainly affected by MGS and SOC content, respectively, in the alpine desert. Combined with the results of the structural equation model, those findings suggest that SOC content affects soil texture under high pH-value (pH 8-9) and that soil microbial biomass is indirectly affected. Soils in the alpine steppe and desert are dominated by plagioclase, which provides colonization sites for bacterial communities. This study aimed to highlight the importance of soil texture in managing soil microbial biomass and demonstrate the differential impacts of soil texture on fungal and bacterial communities in alkaline permafrost-affected regions.

Pyrolytic Evidence for Unsubstituted Aromatics as Potential Oil-Oil/Source Correlation Indicators.

Most oil source correlation indicators are invalid because of the high maturity of the deep marine strata. Thus, a suitable indicator with high thermal stability requires to be established. In this study, to understand the effect of thermal maturation on the carbon isotopic composition of unsubstituted aromatics, we performed a number of anhydrous thermal simulation experiments involving two typical Chinese shales (lacustrine and marine shales), their corresponding expelled oils, three crude oils, and their associated oil fractions, that is, saturates, aromatics, resins, and asphaltenes (SARA). The generated unsubstituted aromatics were examined in terms of molecular distributions and carbon isotopic composition. The results show that unsubstituted aromatics in different types of samples demonstrated similar variation characteristics. Phenanthrene can be formed continuously in 0.45%/0.55-2.30% R o (equivalent vitrinite reflectance), especially in the high-over maturity stage. However, their carbon isotope composition shows minor variations. The unsubstituted aromatic carbon isotopic information in source rocks can be preserved during the whole pyrolysis process. Their carbon isotopic values in source rocks and their corresponding expelled oils are extremely similar. Furthermore, no evident difference exists in the carbon isotopes of unsubstituted aromatics formed by crude oil and associated oil fractions. These results indicate that these types of parameters are suitable for oil-oil/source correlation in deep marine strata with high-over maturity.

Distribution characteristics, source identification, and risk assessment of heavy metals in surface sediments of the salt lakes in the Ordos Plateau, China.

Salt lakes considerably affect the regional climate, environment, and ecology of semiarid regions characterized by low rainfall and high evaporation. However, under the stresses of global change and human disturbance, anthropogenic pollution is the primary factor threatening the lake's ecological environment. Surface sediment samples collected from four salt lakes in the Ordos Plateau were used to investigate the salinity, concentration, pollution status, potential sources of heavy metals, and influencing factors. The surface sediments of Beida Pond and Gouchi Pond were weakly alkaline (pH < 9) due to the presence of Na2SO4, whereas those of Chaigannaoer and Hongjiannao were strongly alkaline (pH > 9) due to the presence of Na2CO3. The concentration range of Cr, Ni, Cu, Zn, As, Cd, and Pb in the sediment samples collected from the salt lakes in the Ordos Plateau followed the order of Cr > Zn > Ni > Pb > Cu > As > Cd. The Cr concentration values were higher in Chagannaoer and Hongjiannao; however, the Ni, Cu, and Zn values were higher in Beida Pond and Gouchi Pond. The geoaccumulation index (Igeo) and enrichment factor (EF) consistently indicated that Cr posed the greatest potential ecological risk and that Ni, Cu, and Zn pollution was more severe in Beida Pond and Gouchi Pond than in Chagannaoer or Hongjiannao. However, the ecological risk index and potential ecological risk value indicated that these heavy metals posed low risks to the environment. The risk assessment code (RAC) revealed that Pb and Cr exhibited no mobility and had low potential bioavailability risk. Meanwhile, Zn, Ni, and As were categorized as medium risk. Cu had the highest mobility and was categorized as high risk. Principal component analysis for the four salt lakes revealed that the source of Ni, Cu, Zn, and Cd might be associated with water-soluble elements associated with aqueous migration, while the source of Cr, Pb, and As might be the lithospheric minerals carried by dust storms. Pearson's correlation analysis indicated that clay minerals were the primary adsorbers of Ni, Cu, Zn, and Cd. Moreover, pH was identified as the main environmental factor controlling the distribution of heavy metals in the salt lakes.

Are oil spills an important source of heavy metal contamination in the Bohai Sea, China?

Accurate evaluation of the heavy metal contamination caused by oil spills is more urgent than that of organic pollution since heavy metals are toxic and persistent. This study applies bulk geochemical parameters and hydrocarbon compositions to explore heavy metal contamination caused by oil spills. The contents of six heavy metals (Cu, Pb, Zn, Cr, Ni, and Co), total organic carbon, aliphatic hydrocarbons, and grain size were measured in 50 subsurface sediment samples obtained from an area affected by oil spills in the Bohai Sea. The values of the contamination factor (CF), the geo-accumulation index (Igeo), and the enrichment factor (EF) indicate moderate contamination with the six investigated heavy metals at most of the sampling sites. Riverine inputs, oil spills, and airborne dust are the three main sources of the heavy metals, and oil spills are the significant source of heavy metal contamination in the areas. The distributions of the mean grain size (Mz) and the contents of unresolved complex mixture (UCM) and Cr suggest that crude oil migrates from deep hydrocarbon reservoirs through geological faults and seeps through coarse-grained sediments until it reaches fine-grained sediments. The spilled oil contributes appreciable amounts of heavy metals to the sediments at the oil-contaminated sites. At these sites, the heavy metals from oil spills overprinted on those contributed by terrigenous materials, which are the predominant source of metals in the subsurface sediments in the areas affected by oil spills.

Distribution and controls of heavy metals and organic matter in the surface sediments of the Southern Yellow Sea, China.

Accurate and effective determination of the source of heavy metals is essential for the treatment of marine ecological environments. This article attempts to combine geochemical composition data and hydrocarbon composition data to achieve this purpose. The concentrations of six heavy metals (Cu, Pb, Zn, Cr, Ni, and Co), grain size, total organic carbon (TOC) content, Al2O3 content, and aliphatic hydrocarbons (AHs) in 501 surface samples from the Southern Yellow Sea (SYS) were analyzed. The results showed that most sample sites ranged from not polluted to moderately polluted. However, Cu, Pb, Cr, and Ni may represent potential hazards, and the toxic probability for the combination of five metals (Cr, Cu, Ni, Zn, and Pb) was 21% for all sampling sites. The highest heavy metal concentrations were associated with the fine-grained sediments in the eastern area, especially in the northeastern muddy area. However, high concentrations of Pb and Cu were also found in some sites with coarse sediment in the western region. The lipid biomarkers showed that the n-alkanes were dominated by large odd-numbered carbon molecules, indicating that the organic matter in the sediments originated mainly from terrestrial plants. Principal component analysis (PCA) results, AH data, and the sediment distributions indicated that the organic matter and heavy metals in the SYS were mainly sourced from the Old Yellow River Delta, transported by ocean currents and deposited in the central SYS. In addition, a small proportion of the heavy metals originated from airborne dust. The spatial distribution pattern of the heavy metals in the surface sediments provides a basis for the protection of the marine ecological environments.

Presence of aliphatic and polycyclic aromatic hydrocarbons in near-surface sediments of an oil spill area in Bohai Sea.

In order to determine the source of organic matter and the fingerprint of the oil components, 50 samples collected from the near-surface sediments of the oil spill area in Bohai Sea, China, were analyzed for grain size, total organic carbon, aliphatic hydrocarbons (AHs), and polycyclic aromatic hydrocarbons (PAHs). The concentrations of C15-35 n-alkanes and 16 United States Environmental Protection Agency (US EPA) priority pollutant PAHs were found in the ranges of 0.88-3.48µg g(-1) and 9.97-490.13ng/g, respectively. The terrestrial organic matters characterized by C27-C35 n-alkanes and PAHs, resulting from the combustion of higher plants, are dominantly contributed from the transportation of these plants by rivers. Marine organic matters produced from plankton and aquatic plants were represented by C17-C26 n-alkanes in AHs. Crude oil, characterized by C17-C21 n-alkanes, unresolved complex mixture (UCM) with a mean response factor of C19 n-alkanes, low levels of perylene, and a high InP/(InP+BghiP) ratio, seeped into the oceans from deep hydrocarbon reservoirs, as a result of geological faults.

An analysis of organic matter sources for surface sediments in the central South Yellow Sea, China: evidence based on macroelements and n-alkanes.

By analyzing the composition of n-alkane and macroelements in the surface sediments of the central South Yellow Sea of China, we evaluated the influencing factors on the distribution of organic matter. The analysis indicates that the distribution of total organic carbon (TOC) was low in the west and high in the east, and TOC was more related to Al2O3 content than medium diameter (MD). The composition of n-alkanes indicated the organic matter was mainly derived from terrestrial higher plants. Contributions from herbaceous plants and woody plants were comparable. The comprehensive analysis of the parameters of macroelements and n-alkanes showed the terrestrial organic matter in the central South Yellow Sea was mainly from the input of the modern Yellow River and old Yellow River. However, some samples exhibited evident input characteristics from petroleum sources, which changed the original n-alkanes of organic matter in sediments.